Asking someone else to make a decision like this, if any metric is sufficient is a problem. After all, this is your work, your thesis, your paper you might decide to write. Only you can make the decision, because it is you who needs to defend the answer. At best, you might choose to ask your thesis advisor or your boss, whatever. And of course, their word would then control what you do. But to say that you made a decision because so-and-so online told you to do it, well, that would never fly.
Of course, there are some "standard" methods to compute the distance between two functions. However you do this, you would be creating a norm, a metric on the vector space of the functions involved.
You mention a dot product. A dot product does not directly measure the difference between elements of vector spaces. It can be used to define a norm. Thus if u and v are two vectors or two functions, then we can write
as a standard Euclidean norm of the difference between them. In the guise of vectors, this is simply computed using dot products, but it is more simply computed with norm, thus norm(u-v). If u and v are truly functions, then the computation requires an integral in theory.
These are of course different things, because one is an integration. Simply taking the norm of the difference of two vectors if they represent functions (I.e., the sqrt of the sum of squares of differences between vectors) is equivalent to using rectangle rule to compute the integral in question. That may be sufficient for your purposes, or it may not. Again, the person to make the decision is you, along with your supervisor.
You might choose to use a more sophisticated measure. But then you might be just wasting your time and effort. TALK TO YOUR SUPERVISOR.
To me, an important question is, how accurately are these PDFs known? Can the simple norm of vector differences as described above adequately resolve any differences between PDFs? Note that if two PDFs are identical, measured on the same support, then the norm of the difference between vectors will be zero. Functions or not, then if your only measurement is the same set of numbers, then the norm must be zero. Were the support of your PDFs different, then you would need to use something more sophisticated to resolve the difference. This is clear.
A problem with computing a simple norm is that norm does not really deal with the difference in terms of PDFs. But here where PDFs are concerned, statistics may come to your aid, in the form of the Kolmogorov-Smirnov test . In the stats toolbox, this is implemented in kstest2, testing if you may reject the hypothesis that two PDFs are the same. A virtue of kstest2 is it tries to assign a p-value to the difference, instead of simply returning a number as a norm of a difference. Were it me, I would strongly consider this option, but I'm not doing your job, nor can I. So, no matter what, you need to discuss this with whoever must help you make the decisions. If you are doing this work on your own, perhaps to write a paper or for whatever purpose, and therefore you have no supervisor, then it all comes down to your own judgment, NOT ours, not anyone online. Again, you will be the one who must defend your decision.